Geopolymer Institute

Promoting the geopolymer science since 1979




Why do geologists see nothing?

This is due to the geological glue, which, though artificial, is seen by the geologists either as an impurity, and therefore useless to study, or as a natural binder. At best, the analysis tools and the working methods of geologists consider the glue as a perfectly natural “micritic binder”. A geologist not informed of geopolymer chemistry will assert with good faith that the stones are natural.

The scientific background, including analysis, formula, stone making, are disclosed in the recently updated book by Prof. Joseph Davidovits Geopolymer Chemistry & Applications, in several chapters, i.e. Chapters 5, 11, 13, 17 and 20.

The chemical formula:

People think that because we use chemicals, it is very easy to find these ingredients in the final product. This is wrong. Thanks to the geopolymer chemistry, the chemical reaction generates natural elements, minerals that can be analysed as natural if scientists are not aware of their artificial nature.

So far, we identified at least two chemical systems, one used for the manufacture of the core blocks (the greatest quantity of stones), the second for the casings. In the recent study by Barsoum, Gangly and Hug , the core blocks are illustrated by the samples MENK, whereas the casings relate to the LAUER and OC samples

1) Chemistry of the core blocks

During geosynthesis kaolinite clay (naturally included in the Giza limestone) first reacts with caustic soda (see chemical formula 2). To manufacture this caustic soda, one uses Egyptian natron (sodium carbonate) and lime (coming from plant ashes) (see chemical formula 1). The so obtained caustic soda, NaOH, will react with clay.

The most interesting point is that this chemical reaction creates also pure limestone (calcite) as well as hydrosodalite (a mineral of the feldspathoids or zeolites family).

But, the mixture is still quite caustic. In order to neutralize it, one adds a special salt called carnallite (magnesium chloride) easily found in evaporites, in saline deposits like natron but not at the same place (see chemical formula 3 and 4). Alkalis have been transformed into neutral salt halite, which explains the high content of NaCl found in pyramid stones.

2) Chemistry of the casing stones

In the chemical formula 2, the clay may be replaced partially (or entirely) by hydrous siliceous mineral varieties, such as diatomaceous earth (hydrated amorphous) yielding sodium silicate (water glass), which will react with carnallite according to chemical formula 3, and formation of magnesium silicate.

The re-agglomerated stone binders are the result of these geosynthesis (geopolymers) that create several natural minerals: limestone (calcite), hydrated feldspars (feldspathoid, mica-chlorite), magnesium silicates, magnesite and halite. Egyptian natron often contains Na-sulfate that yields the formation of Ca-sulfate. We understand why geologists can easily be misled.

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